ChemInform Abstract: Pheromone Synthesis. Part 183. Synthesis of (1R,2R,5S,7R)- and (1R,2S, 5S,7R)-2-Hydroxy-exo-brevicomin, the Components of the Male-Produced Volatiles of the Mountain Pine Beetle, Dendroctonus ponderosae.
โ Scribed by H. TAKIKAWA; K. SHIMBO; K. MORI
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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โฆ Synopsis
Pheromone Synthesis. Part 183. Synthesis of (1R,2R,5S,7R)-and (1R,2S, 5S,7R)-2-Hydroxy-exo-brevicomin, the Components of the Male-Produced Volatiles of the Mountain Pine Beetle, Dendroctonus ponderosae.
-Both title compounds (V) and (VI) are synthesized via asymmetric dihydroxylation as the key step. -(TAKIKAWA, H.; SHIMBO,
๐ SIMILAR VOLUMES
Two components [2-sec-butyl-4,5-dihydrothiazole (1) and were obtained with an enantiomeric purity of ca. 92% ee and were found to be readily racemizable. Asymmetric 3,4-dehydro-exo-brevicomin (2)] of a male-produced pheromone of the mouse Mus musculus have been dihydroxylation was employed as the ke
butoxycarbonyl-2-methylpropanoic acid (D) and (2R,6S)-7acetoxy-2,6-dimethyl-1-heptanol (G), by employing lipase-dodecyl propanoate (1 and 2), the components of the pheromone of Microdiprion pallipes, were synthesized from catalyzed kinetic resolution in a later step. two chiral and nonracemic buildi