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Ternary pnictides MNi2−xPn2 (M ≡ Sr and rare earth metals, Pn ≡ Sb, Bi) with defect CaBe2Ge2 and defect ThCr2Si2 structures

✍ Scribed by W.K Hofmann; W Jeitschko

Book ID
116016783
Publisher
Elsevier Science
Year
1988
Weight
756 KB
Volume
138
Category
Article
ISSN
0022-5088

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Crystal Structure and Bonding in the Rar
Crystal Structure and Bonding in the Rare-Earth Rich Ternary Pnictides RE5M2X (RE=Y, Gd, Tb, Dy, Ho, Er, Tm, Lu; M=Ni, Pd; X=Sb, Bi)
✍ Yurij Mozharivskyj; Hugo F. Franzen 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 316 KB

Eleven new rare-earth antimonides and bismuthides RE 5 M 2 X (see Table 1) have been synthesized and characterized by X-ray powder methods. The compounds are isostructural to the previously reported pnictides RE 5 M 2 X and adopt the Mo 5 B 2 Si structure (space group I4/mcm, an ordered version of C