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Ternary alkaline earth and rare earth metal palladium phosphides with ThCr2Si2- and La6Ni6P17-type structures

โœ Scribed by W. Jeitschko; W.K. Hofmann

Book ID
116014773
Publisher
Elsevier Science
Year
1983
Weight
442 KB
Volume
95
Category
Article
ISSN
0022-5088

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Crystals of the phosphide Ho 2 Cu 6ุŠx P 5ุŠy (x โ€ซุโ€ฌ 0.41, y โ€ซุโ€ฌ 0.50) have been prepared by annealing pressed powders of the elements at 8003C for 2 weeks. The structure was determined by singlecrystal methods: space group R3 m (No. 166), Z โ€ซุโ€ฌ 3, a โ€ซุโ€ฌ 3.976(1) A > , c โ€ซุโ€ฌ 40.554(8) A > , R โ€ซุโ€ฌ 0.04