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Termination Kinetics in Free-Radical Bulk Copolymerization: The Systems Dodecyl Acrylate−Dodecyl Methacrylate and Dodecyl Acrylate−Methyl Acrylate

✍ Scribed by Buback, Michael; Kowollik, Christopher

Book ID
126911124
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
99 KB
Volume
32
Category
Article
ISSN
0024-9297

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Termination kinetics in free-radical bul
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Termination rate coefficients, k t , for the terpolymerization of mixtures containing the three acrylates: methyl, butyl, and dodecyl acrylate or the corresponding members of the methacrylate family: methyl, butyl, and dodecyl methacrylate, have been measured via the single pulse (SP)-PLP technique.

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Pressure dependence of the termination rate coefficient, k t , in the initial period ("plateau region") of methyl acrylate (MA) and dodecyl acrylate (DA) free-radical bulk homopolymerizations at 40 8C. The filled symbols are from ref. [23]

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## Abstract The variation of copolymerization rate with composition obtained for the system methyl acrylate (1)/methyl methacrylate (2)/benzene/2,2′‐azoisobutyronitrile using standard techniques of polymerization rate measurements has been interpreted on the basis of a penultimate effect upon the p