The access to polymeric surfactants via thiol/en addition is investigated, and some synthetic guidelines are established. Surfactant monomers containing two olefinic groups of different reactivity were newly synthesized. They were reacted with various thiols to provide reaction products with well-de
✦ LIBER ✦
Terminal Functionalization of Polypropylene by Radical-Mediated Thiol−Ene Addition
✍ Scribed by Parent, J. Scott; Sengupta, Saurav S.
- Book ID
- 125899119
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 137 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0024-9297
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## Abstract A biodegradable and amphiphilic copolymer, mPEG__‐b‐__P(LA__‐co‐__MAC/TMA) that contains pendant 1,2‐bidentate carboxyl groups is synthesized by thiol‐ene radical addition and is further used to chelate with the active anticancer species (DACH‐Pt) of oxaliplatin to form an mPEG__‐b‐__P(
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