Temperature-jump study of the rate and mechanism of the boric acid-tartaric acid complexation
β Scribed by Kustin, Kenneth; Pizer, Richard
- Book ID
- 126416942
- Publisher
- American Chemical Society
- Year
- 1969
- Tongue
- English
- Weight
- 612 KB
- Volume
- 91
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
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## Abstract The boric acidβcatechol system in aqueous solutions has been studied by means of ^11^B, ^1^H and ^13^C NMR over wide ranges of concentration and pH. ^11^B spectra show a striking difference between the complexation possibilities of dilute and more concentrated solutions of boric acid. B
Growth rates of boric acid have been measured both in the absence and in the presence of electrical field at 1.00 DC voltage as a function of supersaturation in a laboratory-scale fluidized bed crystallizer at the temperature range of 20 Β°C to 52 Β°C. The values of overall rate coefficient (K G ), di