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NMR study of the complexation of boric acid with catechol (1,2-dihydroxybenzene)

✍ Scribed by Maurice Pasdeloup; Colette Brisson


Publisher
John Wiley and Sons
Year
1981
Tongue
English
Weight
343 KB
Volume
16
Category
Article
ISSN
0749-1581

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✦ Synopsis


Abstract

The boric acid–catechol system in aqueous solutions has been studied by means of ^11^B, ^1^H and ^13^C NMR over wide ranges of concentration and pH. ^11^B spectra show a striking difference between the complexation possibilities of dilute and more concentrated solutions of boric acid. Both the 1:1 and 1:2 complexes can be simultaneously observed by ^13^C NMR.


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