The electrical conductance of solutions of hydrogen chloride in dimethylsulphoxide at temperatures from 25 to 45Β°C has been studied. for associated l-l type electrolytes. Results have been interpreted with the Fuoss theory Values of the association constant K, and the J parameter have been computed
Temperature effect in the conductance of hydrogen molecule
β Scribed by M. Crisan; I. Grosu
- Publisher
- Elsevier Science
- Year
- 2008
- Tongue
- English
- Weight
- 118 KB
- Volume
- 41
- Category
- Article
- ISSN
- 1386-9477
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β¦ Synopsis
We present a many-body calculation for the conductance of a conducting bridge of a simple hydrogen molecule between Pt electrodes. The experimental results showed that the conductance G ΒΌ dI=dV has the maximum value near the quantum unit G 0 ΒΌ 2e 2 =h. The I-V dependence presents peak and dip and we consider that the electron-phonon interaction is responsible for this behavior. At T ΒΌ 0 there is a step in this dependence for the energy of phonons o 0 which satisfies eV ΒΌ o 0 . We calculated the conductance at finite temperature and showed that dGΓ°TΓ=dV / 1=4T cosh 2 Γ°eV Γ o 0 Γ=2T.
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