Temperature dependence of the rate constants of cryochemical reactions
β Scribed by G. K. Ivanov; M. A. Kozhushner; L. I. Trakhtenberg
- Book ID
- 105595348
- Publisher
- Springer
- Year
- 1999
- Tongue
- English
- Weight
- 826 KB
- Volume
- 48
- Category
- Article
- ISSN
- 1573-9171
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The objective of this review is to draw attention to potential pitfalls in attempts to glean mechanistic information from the magnitudes of standard enthalpies and entropies derived from the temperature dependence of equilibrium and rate constants for protein interactions. Problems arise because the
## Abstract Absolute rate constants for the reaction of OH with H~2~S have been measured over the temperature range of 239β425 K using the flash photolysisβresonance fluorescence technique. The results showed that the rate constants deviate slightly from Arrhenius behavior but can still be represen