✦ LIBER ✦

Temperature dependence of hydrogen tunnelling rate constants

✍ Scribed by Wilhelm Siebrand; Timothy A. Wildman; Marek Z. Zgierski

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 429 KB
Volume: 98
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(83)87107-3

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Temperature dependence of rate constants

Temperature dependence of rate constants for the reaction of atomic oxygen with hydrogen chloride

✍ Donald L. Singleton; R. J. Cvetanovi 📂 Article 📅 1981 🏛 John Wiley and Sons 🌐 English ⚖ 578 KB

## Abstract A phase‐shift method has been used to determine the rate constant for the reaction of ground state oxygen atoms with HCl over the temperature range of 330–600 K. Oxygen atoms were generated by modulated mercury photosensitized decomposition of N~2~O, and monitored by the chemiluminescen

Interpretation of the temperature depend

Interpretation of the temperature dependence of equilibrium and rate constants

✍ Donald J. Winzor; Craig M. Jackson 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 326 KB

The objective of this review is to draw attention to potential pitfalls in attempts to glean mechanistic information from the magnitudes of standard enthalpies and entropies derived from the temperature dependence of equilibrium and rate constants for protein interactions. Problems arise because the

H + HOONO2 → products: Temperature-depen

H + HOONO2 → products: Temperature-dependent rate constant

✍ Paula L. Trevor; John R. Barker 📂 Article 📅 1981 🏛 John Wiley and Sons 🌐 English ⚖ 563 KB

## Abstract The absolute reaction rate constant of the title reaction was measured in a stirred‐flow reactor under H‐atom‐rich conditions at seven temperatures from 226 to 315 K. Carbon monoxide was added to convert any OH radicals produced back to H atom by way of the reaction OH + CO → H + CO~2~.

Pressure dependence of the low-temperatu

Pressure dependence of the low-temperature tunneling rate for the hydrogen transfer in acridine-doped fluorene crystals

✍ I.Y. Chan; Chung M. Wong; D. Stehlik 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 783 KB

Pressure dependence of the tunneling rate for the hydrogen transfer photoreaction in acridine: fluorene was investigated at 1.4 K. Above 10 kbar, the rate rises exponentially with increasing pressure. These data constitute a measurement of tunneling rate from the vibrational ground state. Its physic

The temperature dependence of dielectric

The temperature dependence of dielectric constants

✍ E.E. Havinga 📂 Article 📅 1961 🏛 Elsevier Science 🌐 English ⚖ 210 KB

Alkaline hydrolysis of cephaloridine: An

Alkaline hydrolysis of cephaloridine: An 1HNMR study. Temperature dependence of the rate constants

✍ B. Vilanova; J. Donoso; F. Muñoz; F. García Blanco 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 545 KB

A kinetic study on the basic hydrolysis of cephaloridine at p D = 10.5 was carried out by using the 'H-NMR technique. Epimerization a t H7, a nucleophilic attack of hydroxyl ion on the p-lactam carbonyl group followed by the release of the pyridine molecule, and isomerization of the double bond at p