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Temperature dependence of the gas-phase reactions F+CHFO, CFO+F, and CFO+CFO

✍ Scribed by Peter Behr; Cornelia Kaupert; Eduard Shafranovski; Horst Heydtmann

Publisher: John Wiley and Sons
Year: 1998
Tongue: English
Weight: 126 KB
Volume: 30
Category: Article
ISSN: 0538-8066
DOI: 10.1002/(sici)1097-4601(1998)30:5<329::aid-kin2>3.0.co;2-u

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✦ Synopsis

The rate coefficients for the reactions and the self-reaction CHFO ϩ F, CFO ϩ F of CFO were determined over the temperature range of A computer controlled 222-298 K. discharge-flow system with mass spectrometric detection was used. The results are expressed in the Arrhenius form (with energies in J): CHFO ϩ F !: CFO ϩ HF: Ϫ12 3 Ϫ1 Ϫ1 k (T) ϭ (9.7 Ϯ 0.7)•10 exp[Ϫ(5940 Ϯ 150)/RT] cm molecule s

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