Temperature dependence of the absolute rate constant for the reaction of ozone with dimethyl sulfide
β Scribed by Hai-tao WANG; Yu-jie ZHANG; Yu-jing MU
- Book ID
- 114335683
- Publisher
- IOS Press
- Year
- 2007
- Tongue
- English
- Weight
- 178 KB
- Volume
- 19
- Category
- Article
- ISSN
- 1878-7320
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π SIMILAR VOLUMES
The rate constants of the gas phase reaction of OH radicals with dimethyl sulfide (CH3SCH3) over the temperature range 260-393 K have been studied using the discharge flow-resonance fluorescence technique. The rate constants were fitted by the Arrhenius equation k = (11.8 2 2.2) x exp[-(236 2 150)/T
Absolute rate constants hav-e been measured for the reaction of SiH, with N,O at temperatures between 295-747 K. The rate constantsarefittedto the Arrheniusequation: log( k/cm' molecule-' s-l) = ( -12.09+0.04) t (2.02?0.31) kJ mol-'JRTln IO. The data are plausibly consistent with a mechanism involv
## Abstract Absolute rate constants for the reaction of OH with H~2~S have been measured over the temperature range of 239β425 K using the flash photolysisβresonance fluorescence technique. The results showed that the rate constants deviate slightly from Arrhenius behavior but can still be represen
Kcccivcd 7 hlarch 1977 The rate constant Ior the rrnction Br + 0~ -BrO + 02 has been mcawrcd over the tempcraturc rdrye 224 to 522 EC in a dxhargc llow systcni ucmk a IKISF spcctrornctcr a~ B detector. Rcsultg, c\pre%scd in the form kr = (3.34 c O-40) X IO-\*' X cxp[ -(978 1. 36)/T] cn13 s-' , arc c