Cross sections and rate constants for the inelastic collision, OH(A2Z+,v=I,j=15) + Ar ~ OH(A2 r.+,v=0,]=20) + Ar, have been calculated in the infinite-order sudden (IOS) and distorted-wave (DW) approximations. The results agree well with experiment.
Temperature dependence of near-resonant vibration ↔ rotation energy transfer
✍ Scribed by D. Frankel; J.I. Steinfeld; R.D. Sharma; L. Poulsen
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- English
- Weight
- 589 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
An expression for the probability of vibration-rotation energy transfer for hydrogen halides was for- mulated by solving the rotational equation of motion. The collision model consists of a rotation-averaged oscillator and a rigid rotator, in which two hydrogen atoms interact strongly in close-in co
## Abstract The contribution of long‐range forces to the observed rates of __V__ → __V__ energy transfer processes has been studied. The theoretical model uses the first order perturbation approximation to generate a probability function, with the dipole–dipole perturbing potential as given by Marg
## Abstract The present study reports the measurement of the V–V energy transfer rates for the CO\*COS system in the temperature range of 195 to 370°K. The measured rates exhibit a slight inverse temperature dependence. The experimental results are compared to prediction based on a model of long‐r