Formulation of vibration-rotation energy transfer probability
โ Scribed by Hyung Kyu Shin
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- English
- Weight
- 435 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
An expression for the probability of vibration-rotation energy transfer for hydrogen halides was for- mulated by solving the rotational equation of motion. The collision model consists of a rotation-averaged oscillator and a rigid rotator, in which two hydrogen atoms interact strongly in close-in collisions to transfer vibrational and rotational energies.
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๐ SIMILAR VOLUMES
A classical model for V-R and V-V energy transfer between two dissimilar diatomic molecules is proposed. For the exponential repulsive potentid, in the limit as the rotation of the mplecules goes to zero, the presenr model reduces to the previous resu!ts for V-T and V-V energy transfer. For the hydr
State-to-state energy transfer cross sections for Ax + HF (u = 2,4, and 6; J = 4.6,8, and 10) were computed using quasi-classic31 trajectories. Rotationat energy transfer is invariant with increasing u, but gyration energy transfer is signi&antiy enhanced by increasing J.