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Vibration-to-rotation and vibration-to-vibration energy transfer between diatomic molecules

✍ Scribed by Lee H. Sentman

Publisher: Elsevier Science
Year: 1973
Tongue: English
Weight: 680 KB
Volume: 18
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(73)80449-x

No coin nor oath required. For personal study only.

✦ Synopsis

A classical model for V-R and V-V energy transfer between two dissimilar diatomic molecules is proposed. For the exponential repulsive potentid, in the limit as the rotation of the mplecules goes to zero, the presenr model reduces to the previous resu!ts for V-T and V-V energy transfer. For the hydrogen halides, whose rchxation is gcnerally accepted as being governed by V-R energy transfer, the Pr's prcdictcd by the present theory agree masonably well with the experimental data. In particular, the positive and negtive temperature dependence of the V-VFr's for N2 -HI and Nz -DI are predicted.

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