We study vrbrarional energy transfer in rnelastic collmear collisions betBeen IWO diaromrc molecules The system is represemed by IWO linearly driven parametric oscillators with a bilinear\_ time-dependent residua1 coupling between them. We amu& for Ihe time evolution of the Irncarly dnvcn par;lmetri
High order corrections to vibrational energy transfer in collisions between two diatomic molecules
โ Scribed by G. Jolicard
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 410 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
This paper analyses the validity of the fist Born approsimation for the study of the vibrational transitions brought about during a collision between two dllltomic molecules. The work shows the importance of the alteration of the mclecular parameters during the collision and the anharmonicity of the potential of the two molecules on the transfers V-T with one quantum and V-V with two quanm.
๐ SIMILAR VOLUMES
## Accurate quantum mechanical transition probabilities for vIbrationa to vibrational and vibrational to translational cncr- gy txm\fcr in collmcar colliaons of two hydrogen molecules were calculated for a model pootentki by numerica integration of the Sduodmgcr equation. The accuracy of these cal
A classical model for V-R and V-V energy transfer between two dissimilar diatomic molecules is proposed. For the exponential repulsive potentid, in the limit as the rotation of the mplecules goes to zero, the presenr model reduces to the previous resu!ts for V-T and V-V energy transfer. For the hydr
An approlimatc approach is dcvelopcd to study the interfcrcncc of one-and twoquantum processes in collinear collisions of an atom and a harmonic oscillator. !n deriving an esplicit espression for vibrational transition probabilities, oncquantum processes arc trcatcd rigorously. while the contributio
possibk RSSOIIS for the non-monotonous tempa-aturs dependencf oE the q~~~d-rescmzm~~ emcrgy trmsf'er probability and relative contributions of short-range and long-range forces are discussed. Particular calcuhtions are made for the caze Nz-C02(v3) vibrational energy exchange.