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Temperature dependence and branching ratio of the C2H5OH+OH reaction

✍ Scribed by U. Meier; H.H. Grotheer; G. Riekert; Th. Just

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
403 KB
Volume
115
Category
Article
ISSN
0009-2614

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✦ Synopsis

Rate consrants of hydrogen abmaction from

CzHsOH by hydroxyl radicals have been measured in the temperature range 300-1000 K by laser-induced fluorescence detection of OH. An Arrhenius evpresslon k(T) = (4.4 f 1.0) x IO-** x exp[(-274 i 90) K/T] cm3/s was derived. Mass spectrometrlc mvestigation of the reaction products resulted in a yield of (75 +. 15)s for the CHJCHOH product channel at 300 K.

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