The effects of a magnelic field of O-ID Ton the huninescence life&me and spectxum of microcrystalline K4[P12(H2P20s)4 ] at 2 K are described\_ The decay lifetime decreases in the presence of a rna~etic field, and Lhe decay becomes non~x~n~ti~\_ The magnetic field also produces a blue-shift in tie lu
Temperature and magnetic-field effects on the luminescence lifetimes of complexes of ruthenium(II) and iridium(III)
β Scribed by R.J. Watts; R.W. Harrigan; G.A. Crosby
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- English
- Weight
- 184 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
β¦ Synopsis
Luminescence Lifetimes of several complex ions at 77% and 4.2'K arc reported. The Lifetimes are shortened in a magnetic field. The results indicate that emission occurs from scvera! states in Boltzmann equilibrium, at least one of which possesses a magnetic moment.
π SIMILAR VOLUMES
Luminescences and excited state lifetimes have been measured for four Ir( I) and Rh(I) complexes at 4 K as a function of magnetic field strength. Induced spectra exhibit a B2 dependence while the lifetimes are a function of Be2.
Assignment of the Triplet Manifolds of d 8 Complexes and Linear Chains via the Effects of Temperature and Magnetic Fields on the Phosphorescence Lifetimes -[Pt(II) complexes; 29 refs.]. -
Dedicated to Professor Jean-Claude BΓΌnzli on the occasion of his 65th birthday The UV, excitation, and luminescence spectra of tris(pivaloyltrifluoroacetonato)europium(III) ([Eu(pta) 3 ]; Hpta ΒΌ 1,1,1-trifluoro-5,5-dimethylhexane-2,4-dione ΒΌ HA) were measured in the presence of bis(salicylidene)tri