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The Role of Isomeric Effects on the Luminescence Lifetimes and Electrochemistry of Oligothienyl-Bridged Dinuclear Tris(2,2′-bipyridine)ruthenium(II) Complexes

✍ Scribed by Robert O. Steen; Lasse J. Nurkkala; Sarah J. Angus-Dunne; Chantal X. Schmitt; Edwin C. Constable; Mark J. Riley; Paul V. Bernhardt; Simon J. Dunne


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
472 KB
Volume
2008
Category
Article
ISSN
1434-1948

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The kinetics of the base hydrolysis of Fe(phen) 3 2ϩ and Fe(bipy) 3 2ϩ (phen ϭ 1,10phenanthroline and bipy ϭ 2,2'-bipyridine) in some aqueous alcohol mixtures at ambient and elevated pressures (up to 1kbar) have been monitored spectrophotometrically at 25.0ЊC. For a given pressure, the alcohol cosol