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ChemInform Abstract: Assignment of the Triplet Manifolds of d8 Complexes and Linear Chains via the Effects of Temperature and Magnetic Fields on the Phosphorescence Lifetimes

✍ Scribed by G. A. CROSBY; K. R. KENDRICK

Publisher: John Wiley and Sons
Year: 2010
Weight: 27 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199837317

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✦ Synopsis

Assignment of the Triplet Manifolds of d 8 Complexes and Linear Chains via the Effects of Temperature and Magnetic Fields on the Phosphorescence Lifetimes -[Pt(II) complexes; 29 refs.]. -

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Luminescence Lifetimes of several complex ions at 77% and 4.2'K arc reported. The Lifetimes are shortened in a magnetic field. The results indicate that emission occurs from scvera! states in Boltzmann equilibrium, at least one of which possesses a magnetic moment.