Temperature and Isotope Dependence of the Reaction of Methyl Radicals with Deuterium Atoms
β Scribed by Seakins, Paul W.; Robertson, Struan H.; Pilling, Michael J.; Wardlaw, David M.; Nesbitt, Fred L.; Thorn, R. Peyton; Payne, Walter A.; Stief, Louis J.
- Book ID
- 127211428
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 278 KB
- Volume
- 101
- Category
- Article
- ISSN
- 1089-5639
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The kinetics of the reaction CHs + OH ( +M ) -CH,OH( + M ) was studied in the temperature range 283-373 K and in the pressure range 85-1000 mbar SF, by pulse radiolysis combined with UV absorption spectroscopy. The methyl and hydroxyl radical decays were followed by monitoring the transient UV absor