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Temperature and deuterium effects on the phosphorescence lifetimes of dimethylbenzaldehydes in durene single crystals

โœ Scribed by A. Despres; V. Lejeune; E. Migirdicyan


Book ID
107941878
Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
823 KB
Volume
66
Category
Article
ISSN
0301-0104

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It is suggested that the hitherto unexplained drastic temperature, pressure and external deuterium isotope effects on the phosphorescence decay-rate constant (kr) of naphthalene in a single crystal of durene can be consistently explained in terms of the photoinduced hydrogen-abstraction reaction of

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Because of interest in the int;amolecula.r hydrogen abstraction that I-benzoyl-8.benzyLnaphthalene undergoes from a triplet state having the x-n\* COn~g~r~~iGn, we also prepared modifications of this molecule where one and two deuterium atoms have replaced the hydrogen atoms of the pl~o~o~bi~e methy