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Tbe chemistry of 7-substituted norbornadienes; 7-cyanonobornadiene and 7-carboxynorbornadiene

โœ Scribed by Gerhard W. Klumpp; Friedrich Bickelhaupt

Publisher
Elsevier Science
Year
1966
Tongue
French
Weight
231 KB
Volume
7
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES

Stereoselectivities of mesitonitrile oxi
Stereoselectivities of mesitonitrile oxide cycloadditions to 7-substituted norbornadienes
โœ Lorenzo Dal Bola; Marco De Amici; Carlo De Micheli; Remo Gandolfi; K.N. Houk ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 249 KB

The stereochemistries of cycloadditions of mesitonitrile oxide to norbomadiene and nine 7-substituted derivatives have been investigated. The stereoselectivities are controlled primarily by torsional effects which are altered by 7-substituents.

Theory of rates and stereoselctivities a
Theory of rates and stereoselctivities and of cycloadditions to 7-substituted norbornadienes.
โœ K.N. Houk; Yun-Dong Wu; Paul H. Mueller; Pierluigi Caramella; Michael N. Paddon- ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 250 KB

The structures of 7-substituted norbomadienes have been studied theoretically with the 3-21G basis set. The stereoselectivities and rates of electrophilic cycloadditions of HCCP to these norbomadienes am rational&d.