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Stereoselectivities of mesitonitrile oxide cycloadditions to 7-substituted norbornadienes

✍ Scribed by Lorenzo Dal Bola; Marco De Amici; Carlo De Micheli; Remo Gandolfi; K.N. Houk

Publisher: Elsevier Science
Year: 1989
Tongue: French
Weight: 249 KB
Volume: 30
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)80619-5

No coin nor oath required. For personal study only.

✦ Synopsis

The stereochemistries of cycloadditions of mesitonitrile oxide to norbomadiene and nine 7-substituted derivatives have been investigated.

The stereoselectivities are controlled primarily by torsional effects which are altered by 7-substituents.

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