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The chemistry of 7-substituted norbornenes 7-ketonorbornene.

✍ Scribed by P.G. Gassman; P.G. Pape

Publisher
Elsevier Science
Year
1963
Tongue
French
Weight
183 KB
Volume
4
Category
Article
ISSN
0040-4039

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The thermal decarbonylation of the 3-cyclopentenone system to the butadiene system has been discussed theoretically (eq. 1). 1 Furthermore, the surprising ease of the thermal decarbonylation of the norbornen-7-one system producinq cyclohexadiene is also well documented (eq. 2).' Recently, we succes

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## Abstract The ruthenium(II)‐catalyzed [2+2] cycloadditions of __anti__ 7‐substituted norbornenes with an alkyne were investigated. The cycloadditions were found to proceed with a high degree of stereoselectivity, giving only the __exo__ stereoisomers in moderate to good yields using an improved p