Two new neutral bicapped bisupporting Keggin-polyoxometalate derivatives: [M(2,2 0 -bpy have been synthesized under hydrothermal conditions by directly using H 4 SiMo 12 O 40 as starting materials. Crystal data for compound 1: C 40 H 36 Co 2 Mo 12 N 8 O 44 SiV 2 , triclinic, space group P 1, a ΒΌ 11
β¦ LIBER β¦
Target Syntheses of Two New Bivanadyl Capped Keggin Polyoxometalate Derivatives
β Scribed by Jingquan Sha; Jun Peng; Shujing Zhou; Min Zhu; Ling Han; Dan Chen
- Book ID
- 106406408
- Publisher
- Springer
- Year
- 2008
- Tongue
- English
- Weight
- 433 KB
- Volume
- 19
- Category
- Article
- ISSN
- 1040-7278
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A new bicapped Keggin polyoxometalate derivative, [Co(phen) phenZ1,10 0 -phenanthroline), has been synthesized under hydrothermal conditions by using H 4 SiMo 12 O 40 as starting materials. Two kinds of crystallographic unique supramolecular chains coexisted in the crystal structure. Single crystal