✦ LIBER ✦

Target synthesis of a new bicapped keggin polyoxometalate derivative: [Co(phen)3]2[SiMoVI8MoV4VIV2O42]·H2O

✍ Scribed by Zhenyu Shi; Xiaojun Gu; Jun Peng; Enbo Wang

Book ID: 103836796
Publisher: Elsevier Science
Year: 2005
Tongue: English
Weight: 191 KB
Volume: 737
Category: Article
ISSN: 0022-2860
DOI: 10.1016/j.molstruc.2004.10.018

No coin nor oath required. For personal study only.

✦ Synopsis

A new bicapped Keggin polyoxometalate derivative, [Co(phen)

phenZ1,10 0 -phenanthroline), has been synthesized under hydrothermal conditions by using H 4 SiMo 12 O 40 as starting materials. Two kinds of crystallographic unique supramolecular chains coexisted in the crystal structure. Single crystal X-ray analysis revealed that compound 1 crystallized in the triclinic system, space group P 1, aZ11.911(4) A ˚, bZ13.726(0) A ˚, cZ14.892(6) A ˚, aZ105.492(2)8, bZ91.358(4)8, gZ97.432(4)8, VZ2322.37(8) A ˚3, ZZ1. Other characterizations by elemental analysis, IR, XPS, ESR and TGA analysis were also described in this paper.

📜 SIMILAR VOLUMES

Hydrothermal Synthesis, Structure Charac

Hydrothermal Synthesis, Structure Characterization of a New Mixed Mo/V Metal-Oxygen Cluster Compound: [Co(phen)3]2 [HPMo4VMo4VIV6IVM2O44]×4H2O, (M = 0.78MoV + 0.22VIV).

✍ Y.-H. Sun; X.-P. Li; D. H. Sun; L. Niu; J.-Q. Xu 📂 Article 📅 2007 🏛 John Wiley and Sons ⚖ 18 KB 👁 1 views

Synthesis and Structural Characterizatio

Synthesis and Structural Characterization of a New Nanoporous-Like Keggin Heteropolyanion Salt: K3(H2O)4 [H2SiVW11O40] (H2O)8+x.

✍ Rodrigo de Paiva Floro Bonfim; Luiza Cristina de Moura; Helene Pizzala; Stefano 📂 Article 📅 2007 🏛 John Wiley and Sons ⚖ 13 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

Hydrothermal synthesis and crystal struc

Hydrothermal synthesis and crystal structure of the novel mixed Mo/V metal–oxygen cluster compound [Co(C2N2H8)3]4[MoV2MoVI14VIV16O80(PO4)2]·10H2O containing the two types of typical heteropoly anions

✍ Yan Xu; Dunru zhu; You Song; Xuefang Zheng; Xiaozeng You 📂 Article 📅 2006 🏛 Elsevier Science 🌐 English ⚖ 231 KB

Synthesis of a New Tetranuclear Cobalt(I

Synthesis of a New Tetranuclear Cobalt(III) Trifluoroacetate Complex [Co4(μ3-O)4(μ-O2CCF3)2(C5H5N)8](ClO4)2

✍ A. N. Belyaev; A. I. Fisher; M. Yu. Gorlov; S. A. Simanova 📂 Article 📅 2004 🏛 Springer 🌐 English ⚖ 20 KB

Hydrothermal synthesis and structure of

Hydrothermal synthesis and structure of a new arsenic–vanadium cluster: [NH2(CH2CH2)2NH2]3[As8V14O42(SO4)]·6.5H2O

✍ Shou-Tian Zheng; Jie Zhang; Guo-Yu Yang 📂 Article 📅 2004 🏛 Elsevier Science 🌐 English ⚖ 270 KB

A new arsenic-vanadium clusters, [NH 2 (CH 2 CH 2 ) 2 NH 2 ] 3 [As 8 V 14 O 42 (SO 4 )]$6.5H 2 O (1), have been hydrothermally synthesized and characterized by IR, elemental analysis, TGA, magnetic property, and single crystal X-ray diffraction analysis. Crystal data: Monoclinic, P2(1)/n, aZ21.963(2

Synthesis, Structure, and Photoluminesce

Synthesis, Structure, and Photoluminescence Property of a New Layered Zirconium Phosphate [Co(dien)2] [Zr4H8P5O26] ×3H2O.

✍ Yu Du; Qinhe Pan; Jiyang Li; Jihong Yu; Ruren Xu 📂 Article 📅 2007 🏛 John Wiley and Sons ⚖ 18 KB 👁 1 views