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Tandem Oxidative Acetalization−Intramolecular Diels−Alder Reactions of 2-Methoxyphenols. Simple Synthesis of Bicyclo[2.2.2]octenone Derivatives

✍ Scribed by Chu, Chrong-Shyua; Lee, Tsung-Ho; Rao, Polisetti Dharma; Song, Ling-Duan; Liao, Chun-Chen


Book ID
127367767
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
111 KB
Volume
64
Category
Article
ISSN
0022-3263

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Syntheses of trienones 2 and 3 and their Diels-Alder reactions with dimethyl acetylenedicarboxylate and benzoquinone are described. The ketone and methyl groups in trienones 2 and 3 appear to be repulsive factors comrolling ~t facial selectivity in their Diels-Alder reactions. Large amounts ofexo ad