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ChemInform Abstract: Generation, Stability, Dimerization, and Diels—Alder Reactions of Masked o-Benzoquinones. Synthesis of Substituted Bicyclo[2.2.2]octenones from 2-Methoxyphenols.

✍ Scribed by Chun-Chen Liao; Chrong-Shyua Chu; Tsung-Ho Lee; Polisetti Dharma Rao; San Ko; Ling-Duan Song; Huey-Chin Shiao

Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

bridged compounds bridged compounds Q

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ChemInform Abstract: Diels—Alder Reactio
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ChemInform Abstract: Synthesis of Stable
ChemInform Abstract: Synthesis of Stable Bromo-Substituted Masked o-Benzoquinones and Their Application to the Synthesis of Bicyclo[2.2.2]octenones.
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## Synthesis of Stable Bromo-Substituted Masked o-Benzoquinones and Their Application to the Synthesis of Bicyclo[2.2.2]octenones. -Oxidation of the brominated phenol (II) in the presence of dienophiles generates adducts (V) via a masked o-benzoquinone. Debromonation of the adducts gives the bicy