## Abstract In the second communication the synthesis of para‐substituted 2‐methyl‐3‐phenylpropen(1)‐carboxylic acid derivatives is described: Phenylacetone compounds are formed by decarboxylation of a glycidicester; these react according to the __Wadsworth__‐__Emmons__ (__Wittig__‐__Horner__)‐reac
Synthetische Juvenilhormone 1. Mitteilung. p-Substituierte β-Methyl-Zimtsäurederivate
✍ Scribed by Albrecht Franke; Günter Mattern; Walter Traber
- Publisher
- John Wiley and Sons
- Year
- 1975
- Tongue
- German
- Weight
- 486 KB
- Volume
- 58
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
In the first communication the synthetic methods are described for preparing aromatic analogues of juvenile hormone like activity. The para‐substituted 2‐methyl‐cinnamic acid derivatives are formed by a Friedel‐Crafts acylation of a phenol, followed by the Wadsworth‐Emmons (Wittig‐Horner)‐Reaction with the corresponding phosphonates. More than 120 compounds are listed.
📜 SIMILAR VOLUMES
## Abstract The synthesis of __p__‐substituted 2‐methyl‐5‐phenyl‐penten(1)‐carboxylic acid derivatives is described: the formed __Grignard__ compounds react with ethylene‐oxide to the corresponding alcohols which are transformed by following reactions to the above mentioned compounds.
## Abstract The syntheses of __p__‐substituted 2‐methyl‐4‐phenylbuten(1)‐carboxylic acid derivatives are described, using __Blanc__'s chloromethylation reaction, the __Friedel__‐__Crafts__ alkylation of unsaturated ketones or the __Meerwein__ arylation; the formed intermediates react in subsequent
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Synthese des 2-Methyl-3,4-(2'-oxo-tetrahydro-imidazol)-thiophans von 0. Sehnider, J.-P. Bourquin und A. Grassner. 1. Mitteilung. (24. 111. 45.)