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Synthetische Juvenilhormone 1. Mitteilung. p-Substituierte β-Methyl-Zimtsäurederivate

✍ Scribed by Albrecht Franke; Günter Mattern; Walter Traber


Publisher
John Wiley and Sons
Year
1975
Tongue
German
Weight
486 KB
Volume
58
Category
Article
ISSN
0018-019X

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✦ Synopsis


Abstract

In the first communication the synthetic methods are described for preparing aromatic analogues of juvenile hormone like activity. The para‐substituted 2‐methyl‐cinnamic acid derivatives are formed by a FriedelCrafts acylation of a phenol, followed by the WadsworthEmmons (WittigHorner)‐Reaction with the corresponding phosphonates. More than 120 compounds are listed.


📜 SIMILAR VOLUMES


Synthetische Juvenilhormone 2. Mitteilun
✍ Albrecht Franke; Günter Mattern; Walter Traber 📂 Article 📅 1975 🏛 John Wiley and Sons 🌐 German ⚖ 421 KB

## Abstract In the second communication the synthesis of para‐substituted 2‐methyl‐3‐phenylpropen(1)‐carboxylic acid derivatives is described: Phenylacetone compounds are formed by decarboxylation of a glycidicester; these react according to the __Wadsworth__‐__Emmons__ (__Wittig__‐__Horner__)‐reac

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## Abstract The syntheses of __p__‐substituted 2‐methyl‐4‐phenylbuten(1)‐carboxylic acid derivatives are described, using __Blanc__'s chloromethylation reaction, the __Friedel__‐__Crafts__ alkylation of unsaturated ketones or the __Meerwein__ arylation; the formed intermediates react in subsequent

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