𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthetische Juvenilhormone 2. Mitteilung. p-Substituierte 2-Methyl-3-phenyl-propen(1)-carbonsäurederivate

✍ Scribed by Albrecht Franke; Günter Mattern; Walter Traber

Publisher
John Wiley and Sons
Year
1975
Tongue
German
Weight
421 KB
Volume
58
Category
Article
ISSN
0018-019X

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

In the second communication the synthesis of para‐substituted 2‐methyl‐3‐phenylpropen(1)‐carboxylic acid derivatives is described: Phenylacetone compounds are formed by decarboxylation of a glycidicester; these react according to the Wadsworth‐Emmons (Wittig‐Horner)‐reaction with the corresponding phosphonates to the title compounds. NMR. data show the formation of the steric isomers of 3‐Phenyl‐2‐methyl‐propen‐1‐ and 3‐Phenyl‐2‐methylpropen‐2‐carboxylic acid derivatives.

📜 SIMILAR VOLUMES

Synthetische Juvenilhormone 3. Mitteilun
Synthetische Juvenilhormone 3. Mitteilung. p-Substituierte 4-Phenyl-buten(1)-carbonsäurederivate
✍ Albrecht Franke; Günter Mattern; Walter Traber 📂 Article 📅 1975 🏛 John Wiley and Sons 🌐 German ⚖ 638 KB

## Abstract The syntheses of __p__‐substituted 2‐methyl‐4‐phenylbuten(1)‐carboxylic acid derivatives are described, using __Blanc__'s chloromethylation reaction, the __Friedel__‐__Crafts__ alkylation of unsaturated ketones or the __Meerwein__ arylation; the formed intermediates react in subsequent

Synthetische Juvenilhormone 4. Mitteilun
Synthetische Juvenilhormone 4. Mitteilung. p-Substituierte 5-Phenyl-penten(1)-carbonsäurederivate
✍ Albrecht Franke; Günter Mattern; Walter Traber 📂 Article 📅 1975 🏛 John Wiley and Sons 🌐 German ⚖ 337 KB

## Abstract The synthesis of __p__‐substituted 2‐methyl‐5‐phenyl‐penten(1)‐carboxylic acid derivatives is described: the formed __Grignard__ compounds react with ethylene‐oxide to the corresponding alcohols which are transformed by following reactions to the above mentioned compounds.

Synthetische Juvenilhormone 1. Mitteilun
Synthetische Juvenilhormone 1. Mitteilung. p-Substituierte β-Methyl-Zimtsäurederivate
✍ Albrecht Franke; Günter Mattern; Walter Traber 📂 Article 📅 1975 🏛 John Wiley and Sons 🌐 German ⚖ 486 KB

## Abstract In the first communication the synthetic methods are described for preparing aromatic analogues of juvenile hormone like activity. The para‐substituted 2‐methyl‐cinnamic acid derivatives are formed by a __Friedel__‐__Crafts__ acylation of a phenol, followed by the __Wadsworth__‐__Emmons

Substituierte 2,8-Diazaspiro[4,5]decan-1
Substituierte 2,8-Diazaspiro[4,5]decan-1, 3-dione. Untersuchungen über synthetische Arzneimittel, 16. Mitteilung
✍ E. Jucker; R. Süess 📂 Article 📅 1966 🏛 John Wiley and Sons 🌐 German ⚖ 752 KB

127. Substituierte 2,8-Diazaspiro[4,5]decan-l, 3-dione Untersuchungen uber synthetische Arzneimittel. 16. Mitteilung [l] von E. Jucker und R. Siiess (12. 11. 66) I) Verbindung I V mit R1 = H und RS = CH,C,H, wurde nach 48stdg. Kochen in konz. Salzsaure zu 55% unverandert zuruckgewonnen, wahrend der