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Synthetic Studies on Thiostrepton: Construction of Thiostrepton Analogues with the Thiazoline-Containing Macrocycle

✍ Scribed by K. C. Nicolaou; Marta Nevalainen; Mark Zak; Stephan Bulat; Marco Bella; Brian S. Safina

Book ID: 101535920
Publisher: John Wiley and Sons
Year: 2003
Tongue: English
Weight: 279 KB
Volume: 115
Category: Article
ISSN: 0044-8249
DOI: 10.1002/ange.200351745

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Synthetic Studies on Thiostrepton Family of Peptide Antibiotics: Synthesis of the Pentapeptide Segment Containing Dihydroxyisoleucine, Thiazoline and Dehydroamino Acid.

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Synthetic studies on the thiostrepton fa

Synthetic studies on the thiostrepton family of peptide antibiotics: synthesis of the tetrasubstituted dehydropiperidine and piperidine cores

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The tetrasubstituted dehydropiperidine and piperidine cores of the thiostrepton family of peptide antibiotics were synthesized which featured the coupling between the azomethine ylide and the enantiopure sulfinimine, and the subsequent stereoselective reduction of the six-membered imine.