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Synthetic studies on rabdosia diterpene lactones II: The synthesis of 15-desoxyeffusin

✍ Scribed by M.J. Kenny; L.N. Mander; S.P. Sethi

Publisher: Elsevier Science
Year: 1986
Tongue: French
Weight: 270 KB
Volume: 27
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)83919-2

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✦ Synopsis

The tricyclic ester 1 was transformed by a sequence of intramolecular Michael and alkylation reactions into the pentacyclic lactone 10 from which the (+)-15-desoxy derivatives of longikaurin C 2 and effusin 4 were then prepared.

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