Synthetic Studies on Chartelline C: Stereoselective Construction of the Core Skeleton
β Scribed by Dr. Kotaro Iwasaki; Rentaro Kanno; Dr. Toshiharu Morimoto; Dr. Tohru Yamashita; Dr. Satoshi Yokoshima; Prof. Tohru Fukuyama
- Book ID
- 118752070
- Publisher
- John Wiley and Sons
- Year
- 2012
- Tongue
- English
- Weight
- 541 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0044-8249
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π SIMILAR VOLUMES
Hydroxypicrasan-3-one, a compound having the correct relative stereochemistry of al1 the six ring-juncture chira1 centers of the picrasane skeleton, was synthesized from a known tricyclic compound, using the orthoester Claisen rearrangement and lead tetraacetate oxidation as key reactions.
Stereoselective construction of the tricyclic core of yonarolide (1), a marine norditerpenoid, was achieved. This synthetic route includes a Diels-Alder reaction and an intramolecular aldol condensation. It also involves efficient epimerization through a retro-Michael reaction-Michael addition and w
A convcrgen~ stesuxon trolled synthesis of lhe cl-c26 podon of laulomyein has been