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Synthetic Reactions by a Complex Catalyst. VI. A Novel Hydrosilation of Isocyanide by Copper Catalyst

✍ Scribed by Saegusa, Takeo.; Ito, Yoshihiko.; Kobayashi, Shiro.; Hirota, Kiwami.

Book ID: 120483965
Publisher: American Chemical Society
Year: 1967
Tongue: English
Weight: 261 KB
Volume: 89
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00985a052

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Synthetic reaction by complex catalyst I

Synthetic reaction by complex catalyst IV. Copper catalyzed reaction of alcohol with isocyanide

✍ Takeo Saegusa; Yoshihiko Ito; Shiro Kobayashi; Kiwami Hirota 📂 Article 📅 1967 🏛 Elsevier Science 🌐 French ⚖ 178 KB

Recently we have explored a series of copper catalyzed reactions of amine with isocyanide 1) \_ (es. (ill, carbon monoxide 2) (eq. (ii)), diazomethane 3) (en. (iii)), and ethyl diazoacetate 3) (eq. (iv)).

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In the preceding communication (l), we have reported that primary and secondary amines react with isocyanide in the presence of copper compound as the catalyst to produce amidines in almost quantitative yields. ## N-R " In view of the fact that carbon monoxide is isoelectronic with isocyanide (2)