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Synthetic reaction by complex catalyst IV. Copper catalyzed reaction of alcohol with isocyanide

✍ Scribed by Takeo Saegusa; Yoshihiko Ito; Shiro Kobayashi; Kiwami Hirota

Publisher: Elsevier Science
Year: 1967
Tongue: French
Weight: 178 KB
Volume: 8
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)90541-0

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✦ Synopsis

Recently we have explored a series of copper catalyzed reactions of amine with isocyanide 1) _ (es. (ill, carbon monoxide 2) (eq. (ii)), diazomethane 3) (en.

(iii)), and ethyl diazoacetate 3) (eq. (iv)).

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In the preceding communication (l), we have reported that primary and secondary amines react with isocyanide in the presence of copper compound as the catalyst to produce amidines in almost quantitative yields. ## N-R " In view of the fact that carbon monoxide is isoelectronic with isocyanide (2)

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Recently we have reported that in the presence of cuprous chloride as catalyst isocyanide (I) reacts with p,r-unsaturated alcohol (II) to produce the corresponding formimidate (III)l).