Synthetic reaction by complex catalyst iii. Copper catalyzed n-alkylation of amine with diazoalkie
β Scribed by Takeo Saegusa; Yoshihiko Ito; Shiro Kobayashi; Kiwami Hirota; Toyoji Shimizu
- Publisher
- Elsevier Science
- Year
- 1966
- Tongue
- French
- Weight
- 129 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
In the preceding communication (l), we have reported that primary and secondary amines react with isocyanide in the presence of copper compound as the catalyst to produce amidines in almost quantitative yields. ## N-R " In view of the fact that carbon monoxide is isoelectronic with isocyanide (2)
Recently we have explored a series of copper catalyzed reactions of amine with isocyanide 1) \_ (es. (ill, carbon monoxide 2) (eq. (ii)), diazomethane 3) (en. (iii)), and ethyl diazoacetate 3) (eq. (iv)).
A new effective catalytic system consisting of [Cp\*IrCl 2 ] 2 /K 2 CO 3 (Cp\*=pentamethylcyclopentadienyl) for the N-alkylation of primary amines with alcohols has been developed. As an example, the reaction of aniline with benzyl alcohol in the presence of [Cp\*IrCl 2 ] 2 (5.0 mol%Ir) and K 2 CO 3
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v