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Synthetic approaches to 10-epieudesmane sesquiterpenes. A synthesis of intermedeol

✍ Scribed by Huffman, J. W.; Miller, C. A.; Pinder, A. R.

Book ID
126911848
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
963 KB
Volume
41
Category
Article
ISSN
0022-3263

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A biomimetic type synthesis of (+)-ranulosin from the acyclic precursorAis described. Mercury mediated oxidative cyclization and bromolactonization are shown to be useful for the construction of the actinobolin skeleton.