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Approaches to Sesquiterpenes Containing Three Contiguous Quaternary Carbon Atoms. Synthesis of 3-Methoxythapsene.

โœ Scribed by A. Srikrishna; D. B. Ramachary


Publisher
John Wiley and Sons
Year
2005
Weight
31 KB
Volume
36
Category
Article
ISSN
0931-7597

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โœฆ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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ฮฒ-elimination of protected aldono-1,4-la
โœ Gerrit Limberg; Joachim Thiem ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 527 KB

The well-known /3-elimination of protected aldonolactones is used for the synthesis of the short-chain 2-keto-3-deoxyaldonic acids 1-4 containing four to six carbon atoms. The key step is the facile /3-elimination step which generates the desired 2-keto-3-deoxy acids as protected enoi 1,4-1actones i