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A synthetic approach to actinobolin. Total synthesis of (±)-ramulosin

✍ Scribed by Robert Cordova; Barry B. Snider

No coin nor oath required. For personal study only.

✦ Synopsis

A biomimetic type synthesis of (+)-ranulosin from the acyclic precursorAis described.

Mercury mediated oxidative cyclization and bromolactonization are shown to be useful for the construction of the actinobolin skeleton.

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