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Synthetic applications of radical ring-opening: use of cyclopropylmethyl radicals

โœ Scribed by Clive, Derrick L. J.; Daigneault, Sylvain


Book ID
121190102
Publisher
The Royal Society of Chemistry
Year
1989
Tongue
English
Weight
449 KB
Volume
6
Category
Article
ISSN
0022-4936

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Radical emulsion polymerizations of vinylcyclopropanes, 1,1-bis(ethoxycarbonyl)-2-vinylcyclopropane (ECVCP) and 1,1-dichloro-2-vinylcyclopropane (CVCP) were examined. ECVCP underwent soap-free and soap-in emulsion polymerizations satisfactorily to afford the ring-opened polymer in good yields. Polym