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An electron spin resonance study of the ring-opening of silyl-substituted cyclopropylmethyl radicals

✍ Scribed by Alwyn G. Davies; Jalal A.-A. Hawari; Micheline Grignon-Dubois; Michel Pereyre

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
609 KB
Volume
255
Category
Article
ISSN
0022-328X

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πŸ“œ SIMILAR VOLUMES

The role of alkyl substitution on the sp
The role of alkyl substitution on the spin distribution in the radical cation of alkyl-cyclohexane: An electron-spin-resonance study
✍ Kazumi Toriyama; Kaoru Matsuura; Keichi Nunome πŸ“‚ Article πŸ“… 1990 πŸ› Elsevier Science 🌐 English βš– 475 KB

The role of alkyl substitution on the electronic structure of cyclohexane radical cation was investigated with low-temperature matrix ESR and semiempirical MO calculations. It was found that the unpaired electron, which is originally delocalized throughout the cyclohexane ring, tends to be confined