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Synthesis, X-ray structure and rearrangement of nitrogen ylides obtained upon alkyne and CO insertion reactions into aminocarbene complexes of chromium

✍ Scribed by Rudler, H.; Parlier, A.; Goumont, R.; Daran, J. C.; Vaissermann, J.


Book ID
120264593
Publisher
The Royal Society of Chemistry
Year
1991
Tongue
English
Weight
337 KB
Volume
16
Category
Article
ISSN
0022-4936

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BH, containing iron complexes Fe(q'-HB(H),SCHSR')(CO)(PR,), (3) were prepared by reduction of Fe(q'-CS,R')(X)(CO)(PR& derivatives (2) with NaBH,. The X-ray structure of 3a (R' = R = Me) shows the cis addition of the H-and BH, fragments to the coordinated dithioformate C-S bond and that one B-H bond