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Palladium-Assisted Formation of Carbon−Carbon Bonds. 4. 1 Synthesis and Reactivity of a Water-Soluble (2,3,4-Trimethoxy-6-(ethoxymethyl)phenyl)palladium(II) Complex. Reactions with Alkynes of Its Derivatives: Further Insight into the Pathway of Formation of Highly Functionalized Organic Spirocycles and X-ray Structures of Model Intermediates

✍ Scribed by Vicente, José; Abad, José-Antonio; Fernández-de-Bobadilla, Rocío; Jones, Peter G.; Ramírez de Arellano, M. Carmen

Book ID
118744378
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
663 KB
Volume
15
Category
Article
ISSN
0276-7333

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Palladium-Assisted Formation of Carbon−C
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Palladium-Assisted Formation of Carbon−C
Palladium-Assisted Formation of Carbon−Carbon Bonds. 7. 1 Reactions of (2,3,4-Trimethoxy-6-X-phenyl)palladium Complexes with Alkynes (X = C(O)NHBu t ) and Isocyanides (X = C(O)NHBu t , C(O)Me, CHO): Crystal and Molecular Structures of [Pd{C 6 H{C(O)NHBu t }-6-(OMe) 3 -2,3,4}(bpy)](CF 3 SO 3 ), [Pd{C(CO 2 Me)C(CO 2 Me)C 6 H{C(O)NHBu t }-6-(OMe) 3 -2,3,4)}- Cl(PPh 3 )], [Pd{C(NXy)C 6 H{C(O)NHBu t }-6-(OMe) 3 -2,3,4}- (bpy)](CF 3 SO 3 ), and the Ketenimine 2-(2,6-Dimethylphenyl)-1-(((2,6-dimethylphenyl)imino)- methylene)-5,6,7-trimethoxy-3-oxoisoindoline
✍ Vicente, José; Abad, José-Antonio; Shaw, Kenneth F.; Gil-Rubio, Juan; Ramírez de 📂 Article 📅 1997 🏛 American Chemical Society 🌐 English ⚖ 527 KB