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Fragmentation reactions ofN-sulfinylaniline PhNSO by the dinuclear complex [Fe2(CO)7{μ-C(R)C(NEt2)}]: Nitrene and sulfur insertions into iron carbene bonds. Synthesis and x-ray structures of [Fe2(CO)6{μ-N(Ph)C(NEt2)C(Me)S}] [Fe2(CO)6{μ-N(Ph)C(NEt2)C(Ph)S}] · 0.5C6H14and [Fe2(CO)6{μ-C(C3H5)C(NEt2)N(Ph)SO}] · 0.5CH2Cl2

✍ Scribed by Jean-Claude Daran; Bernd Heim; Yves Jeannin

Publisher: Springer
Year: 1993
Tongue: English
Weight: 912 KB
Volume: 4
Category: Article
ISSN: 1040-7278
DOI: 10.1007/bf00703734

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