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Synthesis via sigmatropic rearrangement. 12. Total synthesis of (+)-dihydrocostunolide via tandem Cope-Claisen rearrangement

✍ Scribed by Raucher, Stanley; Chi, Ki Whan; Hwang, Ki Jun; Burks, John E.

Book ID
126988294
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
294 KB
Volume
51
Category
Article
ISSN
0022-3263

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Synthesis of chiral crownophanes via tan
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✍ Hideo Tokuhisa; Yoshinobu Nagawa; Hirotaka Uzawa; Kazuhisa Hiratani πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 245 KB

A synthetic route for crownophanes containing a chiral binaphthyl unit using tandem Claisen rearrangement is described to demonstrate the versatility of this approach. Molecular recognition by the resulting crownophane for butylurea is also investigated.