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Synthesis of chiral crownophanes via tandem Claisen rearrangement

✍ Scribed by Hideo Tokuhisa; Yoshinobu Nagawa; Hirotaka Uzawa; Kazuhisa Hiratani

Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 245 KB
Volume: 40
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(99)01662-7

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✦ Synopsis

A synthetic route for crownophanes containing a chiral binaphthyl unit using tandem Claisen rearrangement is described to demonstrate the versatility of this approach. Molecular recognition by the resulting crownophane for butylurea is also investigated.

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