Large single crystals of the polar, hydrated pentaborates Me[B 5 O 6 (OH) 4 ]•2H 2 O (Me = Rb, NH 4 ) were grown from aqueous solutions. The structure of NH 4 [B 5 O 6 (OH) 4 ]•2H 2 O was redetermined and proved to be orthorhombic (space group Aba2 (No. 41) with a = 11.3192(7) Å, b = 11.0261(8) Å, c
Synthesis, thermal properties and structural characterisation, of the tetraphenylphosphonium pentaborate salt, [PPh4][B5O6(OH)4]·1.5H2O
✍ Scribed by Michael A. Beckett; Peter N. Horton; Michael B. Hursthouse; James L. Timmis; K. Sukumar Varma
- Book ID
- 113642390
- Publisher
- Elsevier Science
- Year
- 2012
- Tongue
- English
- Weight
- 550 KB
- Volume
- 383
- Category
- Article
- ISSN
- 0020-1693
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The crystal structure of synthetic Rb 2 [B 4 O 5 (OH) 4 ] ' 3.6H 2 O has been established from single-crystal X-ray di4raction data. It crystallizes in the orthorhombic space group Pbcn with a unit cell of dimensions a ؍ 11.276(5) A s , b ؍ 13.097(14) A s , c ؍ 16.751(5) A s ; V ؍ 2474(3) A