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ChemInform Abstract: Crystal Growth and Optical Properties of the Polar Hydrated Pentaborates Rb[B5O6(OH)4]×2H2O and NH4 [B5O6(OH)4]×2H2O and Structure Redetermination of the Ammonium Compound.

✍ Scribed by P. Becker; P. Held; L. Bohaty


Publisher
John Wiley and Sons
Year
2001
Weight
34 KB
Volume
32
Category
Article
ISSN
0931-7597

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Abstract

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Crystal Growth and Optical Properties of
✍ P. Becker; P. Held; L. Bohatý 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 260 KB 👁 2 views

Large single crystals of the polar, hydrated pentaborates Me[B 5 O 6 (OH) 4 ]•2H 2 O (Me = Rb, NH 4 ) were grown from aqueous solutions. The structure of NH 4 [B 5 O 6 (OH) 4 ]•2H 2 O was redetermined and proved to be orthorhombic (space group Aba2 (No. 41) with a = 11.3192(7) Å, b = 11.0261(8) Å, c