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Synthesis, crystal structure and NLO property of a nonmetal pentaborate [C6H13N2][B5O6(OH)4]

✍ Scribed by Huan-Xin Liu; Yun-Xiao Liang; Xiao Jiang


Book ID
108195636
Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
449 KB
Volume
181
Category
Article
ISSN
0022-4596

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Large single crystals of the polar, hydrated pentaborates Me[B 5 O 6 (OH) 4 ]β€’2H 2 O (Me = Rb, NH 4 ) were grown from aqueous solutions. The structure of NH 4 [B 5 O 6 (OH) 4 ]β€’2H 2 O was redetermined and proved to be orthorhombic (space group Aba2 (No. 41) with a = 11.3192(7) Γ…, b = 11.0261(8) Γ…, c